GCSE Science | Structure and Bonding

Ionic bonding

  • between a metal and a non-metal
  • the electrostatic attraction between a metal and a non-metal ion

Examples of ionic structures

  • sodium chloride, sodium oxide, magnesium chloride, aluminium oxide

Diagram

Explanation in terms of ions and movement of electrons

  • Magnesium loses two electrons
  • to become a 2+ ion
  • Oxygen gains two electrons
  • to become a 2- ion
  • There is electrostatic attraction between the opposite ions.

Properties

  • high mp/ bp
    • strong electrostatic attraction between opposite ions
    • which requires a lot of energy to overcome
  • it conducts electricity when molten
    • ions are free to move
    • so they can carry charge
  • it doesn't conduct electricity when solid
    • ions are not free to move
    • so they cannot carry charge

Covalent bonding

  • between non-metal and non-metal
  • a shared pair of electrons

Examples of simple covalent molecules

  • carbon dioxide, oxygen, water, nitrogen oxide

Diagram

Properties of a simple covalent molecule

  • low mp/ bp
    • weak intermolecular forces which
    • requires less energy to overcome
  • does not conduct electricity
    • no delocalised electrons
    • not free to move
    • not able to carry charge

Examples of giant covalent structures

  • diamond, graphite, graphene, fullerenes

Structure of giant covalent structures

  • all of these are made of carbon atoms covalently bonded to each other
  • diamond - each carbon atom is bonded to 4 other carbon atoms
  • graphite - each carbon atom is bonded to 3 other carbon atoms
  • graphene - same as graphite, but only one single layer

Properties of giant covalent structures

  • high mp/ bp
    • lots of strong covalent bonds
    • lots of energy required to overcome
  • diamond does not conduct electricity
    • no delocalised electrons
    • not free to move
    • cannot carry charge
  • graphite/ graphene does conduct electricity
    • delocalised electrons
    • free to move
    • can carry charge
  • graphite is slippery
    • weak intermolecular forces between layers
    • layers can slide over each other

Metallic bonding

Alloys

  • mixture of two or metals
  • harder than pure metals
    • particles are different sizes
    • particles are not arranged in neat rows and columns
    • cannot slide over each other if hammered

Triple Science Only

Nanoparticles

  • very high surface area to volume ratio
  • useful for catalysts, medicine, electronics

Risks of using nanoparticles

  • can be breathed in/ enter cells and catalyse harmful reactions
  • toxic substances can easily bind to them due to large surface area per cm3
  • recent development so lack of scientific research